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Nanoporous Amorphous Carbon Monolayer Derived from Fullerene Film.

ABSTRACT: Carbon materials derived from fullerene are reported recently with unique structures and properties. However, only micrometer size samples can be obtained that limits the studying and exploration for membrane applications. Here, the preparation of a centimeter-size nanoporous amorphous carbon monolayer is reported by rapid pyrolyzing a Langmuir-Blodgett film of fullerene. The sample is fully characterized and the results indicate that the amorphous carbon monolayer derived from fullerene is metastable and insulating. The ionic transmembrane transport study demonstrates that the membrane is porous and cation selective with a selectivity of 26%. This work provides new insights into the controlled synthesis of large-size metastable amorphous carbon monolayer.

SUBMITTER: He M

PROVIDER: S-EPMC10933613 | biostudies-literature | 2024 Mar

REPOSITORIES: biostudies-literature

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Nanoporous Amorphous Carbon Monolayer Derived from Fullerene Film.

He Meng M Ding Yehui Y Liu Xue X

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20231228 10

Carbon materials derived from fullerene are reported recently with unique structures and properties. However, only micrometer size samples can be obtained that limits the studying and exploration for membrane applications. Here, the preparation of a centimeter-size nanoporous amorphous carbon monolayer is reported by rapid pyrolyzing a Langmuir-Blodgett film of fullerene. The sample is fully characterized and the results indicate that the amorphous carbon monolayer derived from fullerene is meta ...[more]

PMID: 38155485

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Project description:The energy storage performances of supercapacitors are expected to be enhanced by the use of nanostructured hierarchically micro/mesoporous hollow carbon materials based on their ultra-high specific surface areas and rapid diffusion of electrolyte ions through the interconnected channels of their mesoporous structures. In this work, we report the electrochemical supercapacitance properties of hollow carbon spheres prepared by high-temperature carbonization of self-assembled fullerene-ethylenediamine hollow spheres (FE-HS). FE-HS, having an average external diameter of 290 nm, an internal diameter of 65 nm, and a wall thickness of 225 nm, were prepared by using the dynamic liquid-liquid interfacial precipitation (DLLIP) method at ambient conditions of temperature and pressure. High temperature carbonization (at 700, 900, and 1100 °C) of the FE-HS yielded nanoporous (micro/mesoporous) hollow carbon spheres with large surface areas (612 to 1616 m2 g-1) and large pore volumes (0.925 to 1.346 cm3 g-1) dependent on the temperature applied. The sample obtained by carbonization of FE-HS at 900 °C (FE-HS_900) displayed optimum surface area and exhibited remarkable electrochemical electrical double-layer capacitance properties in aq. 1 M sulfuric acid due to its well-developed porosity, interconnected pore structure, and large surface area. For a three-electrode cell setup, a specific capacitance of 293 F g-1 at a 1 A g-1 current density, which is approximately 4 times greater than the specific capacitance of the starting material, FE-HS. The symmetric supercapacitor cell was assembled using FE-HS_900 and attained 164 F g-1 at 1 A g-1 with sustained 50% capacitance at 10 A g-1 accompanied by 96% cycle life and 98% coulombic efficiency after 10,000 consecutive charge/discharge cycles. The results demonstrate the excellent potential of these fullerene assemblies in the fabrication of nanoporous carbon materials with the extensive surface areas required for high-performance energy storage supercapacitor applications.

Dataset Information

Nanoporous Amorphous Carbon Monolayer Derived from Fullerene Film.

Publications

Nanoporous Amorphous Carbon Monolayer Derived from Fullerene Film.

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