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A Silver Nanocluster Assembled by a Superatomic Building Unit.

ABSTRACT: A unique assembly of a two-electron superatom, [Ag₁₀{S₂P(OⁱPr)₂}₈], as a primary building unit in the construction of a supramolecule [Ag₁₀{S₂P(OⁱPr)₂}₈]₂(μ-4,4'-bpy) through a 4,4'-bipyridine (4,4'-bpy) linker is reported. This approach is facilitated by an open site in the structure that allows for effective pairing. The assembled structure demonstrates a minimal solvatochromic shift across organic solvents with variable polarities, highlighting the influence of self-assembly on the photophysical properties of silver nanoclusters.

SUBMITTER: Yen WJ

PROVIDER: S-EPMC10966729 | biostudies-literature | 2024 Mar

REPOSITORIES: biostudies-literature

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A Silver Nanocluster Assembled by a Superatomic Building Unit.

Yen Wei-Jung WJ Liao Jian-Hong JH Chiu Tzu-Hao TH Wen Yuh-Sheng YS Liu C W CW

Inorganic chemistry 20240312 12

A unique assembly of a two-electron superatom, [Ag10{S2P(OiPr)2}8], as a primary building unit in the construction of a supramolecule [Ag10{S2P(OiPr)2}8]2(μ-4,4'-bpy) through a 4,4'-bipyridine (4,4'-bpy) linker is reported. This approach is facilitated by an open site in the structure that allows for effective pairing. The assembled structure demonstrates a minim ...[more]

PMID: 38468603

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