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A polyphosphazene elastomer containing 2,2,2-trifluoroethoxy groups as a dielectric in electrically responsive soft actuators.


ABSTRACT: The adaptive structure and excellent actuation of dielectric elastomer actuators (DEAs) make them promising candidates for soft robotics, haptic interfaces and artificial muscles. A wide variety of elastomers have been synthesised and investigated as dielectrics. Inorganic polymers such as polysiloxanes and polyphosphazenes have a low glass transition temperature. While polydimethylsiloxane (PDMS) has made its way into DEAs, the latter has received little attention in this field. Here, we present a dielectric elastomer based on polyphosphazene modified with 2,2,2,-trifluoroethoxy groups as the dielectric, which exhibits a dielectric permittivity two times higher than polydimethylsiloxanes (PDMS), excellent elasticity and a high dielectric breakdown field. These properties enable fast, reliable actuation and higher electrostatic forces than conventional PDMS. The actuators can withstand repeated actuation cycles and are suitable for long-term reliability applications.

SUBMITTER: Karaman CZ 

PROVIDER: S-EPMC11340341 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature

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A polyphosphazene elastomer containing 2,2,2-trifluoroethoxy groups as a dielectric in electrically responsive soft actuators.

Karaman Cansu Zeytun CZ   Venkatesan Thulasinath Raman TR   von Szczepanski Johannes J   Nüesch Frank A FA   Opris Dorina M DM  

Journal of materials chemistry. C 20240711 33


The adaptive structure and excellent actuation of dielectric elastomer actuators (DEAs) make them promising candidates for soft robotics, haptic interfaces and artificial muscles. A wide variety of elastomers have been synthesised and investigated as dielectrics. Inorganic polymers such as polysiloxanes and polyphosphazenes have a low glass transition temperature. While polydimethylsiloxane (PDMS) has made its way into DEAs, the latter has received little attention in this field. Here, we presen  ...[more]

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