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Novel truxene-based dipyrromethanes (DPMs): synthesis, spectroscopic characterization and photophysical properties.

ABSTRACT: For the first time, herein, we report the synthetic part of the truxene-centred mono-, di- and tri-substituted dipyromethanes (DPMs) in good yields (60-80%) along with their preliminary photophysical (absorption, emission and time resolved fluorescence lifetime) properties. The condensation reaction for assembling the required DPMs were catalyzed with trifluoroacetic acid (TFA) at 0 °C to room temperature (rt), and the stable dipyrromethanes were purified through silica-gel column chromatography. After successfully synthesizing these easy-to-make yet interesting molecules, they were fully characterized by means of the standard spectroscopic techniques (¹H NMR, ¹³C NMR and HRMS). We are of the opinion that these truxene-based systems will be useful for diverse applications in future studies.

SUBMITTER: Alvi S

PROVIDER: S-EPMC11368050 | biostudies-literature | 2024

REPOSITORIES: biostudies-literature

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Novel truxene-based dipyrromethanes (DPMs): synthesis, spectroscopic characterization and photophysical properties.

Alvi Shakeel S Ali Rashid R

Beilstein journal of organic chemistry 20240829

For the first time, herein, we report the synthetic part of the truxene-centred mono-, di- and tri-substituted dipyromethanes (DPMs) in good yields (60-80%) along with their preliminary photophysical (absorption, emission and time resolved fluorescence lifetime) properties. The condensation reaction for assembling the required DPMs were catalyzed with trifluoroacetic acid (TFA) at 0 °C to room temperature (rt), and the stable dipyrromethanes were purified through silica-gel column chromatography ...[more]

PMID: 39224227

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