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Stereoselective Synthesis of Cyclometalated Iridium (III) Complexes: Characterization and Photophysical Properties.


ABSTRACT: The stereoselective synthesis of a highly luminescent neutral Ir(III) complex comprising two bidentate chiral, cyclometalating phenylpyridine derivatives, and one acetylacetonate as ligands is described. The final complex and some intermediates were characterized by X-ray structural analysis, NMR-, CD-, and CPL-spectroscopy.

SUBMITTER: Yang L 

PROVIDER: S-EPMC2711639 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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Stereoselective Synthesis of Cyclometalated Iridium (III) Complexes: Characterization and Photophysical Properties.

Yang Liangru L   von Zelewsky Alex A   Nguyen Huong P HP   Muller Gilles G   Labat Gaël G   Stoeckli-Evans Helen H  

Inorganica chimica acta 20090801 10


The stereoselective synthesis of a highly luminescent neutral Ir(III) complex comprising two bidentate chiral, cyclometalating phenylpyridine derivatives, and one acetylacetonate as ligands is described. The final complex and some intermediates were characterized by X-ray structural analysis, NMR-, CD-, and CPL-spectroscopy. ...[more]

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