Synthesis and characterization of chlorotriarylbismuthonium salts.
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ABSTRACT:
SUBMITTER: Kuziola J
PROVIDER: S-EPMC11372555 | biostudies-literature | 2024 Sep
REPOSITORIES: biostudies-literature
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Synthesis and characterization of chlorotriarylbismuthonium salts.
Kuziola Jennifer J Nöthling Nils N Leutzsch Markus M Cornella Josep J
Chemical communications (Cambridge, England) 20240920 76
This work reports the synthesis and structural study of a family of chlorotriarylbismuthonium salts. The abstraction of a chlorine atom with NaBAr<sup>F</sup> from triarylbismuth dichloride species leads to monomeric and dimeric chlorotriarylbismuthonium species, which show a distinct behavior in solution and solid-state in comparison to their fluorotriarylbismuthonium analogues. ...[more]
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