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A superior P-H phosphonite: asymmetric allylic substitutions with fenchol-based palladium catalysts.

ABSTRACT: The fenchol-based P-H phosphonite BIFOP-H exeeds with 65% ee other monodentate ligands in the Pd-catalyzed substitution of 1-phenyl-2-propenyl acetate with dimethylmalonate.

SUBMITTER: Goldfuss B

PROVIDER: S-EPMC1479457 | biostudies-literature | 2006 Mar

REPOSITORIES: biostudies-literature

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A superior P-H phosphonite: asymmetric allylic substitutions with fenchol-based palladium catalysts.

Goldfuss Bernd B Löschmann Thomas T Kop-Weiershausen Tina T Neudörfl Jörg J Rominger Frank F

Beilstein journal of organic chemistry 20060330

The fenchol-based P-H phosphonite BIFOP-H exeeds with 65% ee other monodentate ligands in the Pd-catalyzed substitution of 1-phenyl-2-propenyl acetate with dimethylmalonate. ...[more]

PMID: 16573833

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