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M-Iodosylbenzoic acid - a convenient recyclable reagent for highly efficient aromatic iodinations.

ABSTRACT: m-Iodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion exchange resin or from the basic aqueous solution by simple acidification with HCl.

SUBMITTER: Kirschning A

PROVIDER: S-EPMC1924527 | biostudies-literature | 2007 Jun

REPOSITORIES: biostudies-literature

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m-Iodosylbenzoic acid - a convenient recyclable reagent for highly efficient aromatic iodinations.

Kirschning Andreas A Yusubov Mekhman S MS Yusubova Roza Y RY Chi Ki-Whan KW Park Joo Y JY

Beilstein journal of organic chemistry 20070604

m-Iodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion exchange resin or from the basic aqueous solution by simple acidification with HCl. ...[more]

PMID: 17543133

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