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Synthetic studies toward the bryostatins: a substrate-controlled approach to the A-ring.

ABSTRACT: [reaction: see text] The synthesis of a C1-C13 A-ring subunit of bryostatin 1 is detailed. The key features of the approach include the convergent fragment assembly with a highly stereoselective construction of the C7-C8 bond indicated above.

SUBMITTER: Keck GE 

PROVIDER: S-EPMC2516405 | biostudies-literature | 2006 Aug

REPOSITORIES: biostudies-literature

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Synthetic studies toward the bryostatins: a substrate-controlled approach to the A-ring.

Keck Gary E GE   Welch Dennie S DS   Vivian Paige K PK  

Organic letters 20060801 17

[reaction: see text] The synthesis of a C1-C13 A-ring subunit of bryostatin 1 is detailed. The key features of the approach include the convergent fragment assembly with a highly stereoselective construction of the C7-C8 bond indicated above. ...[more]

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