Ontology highlight
ABSTRACT:
SUBMITTER: Baati R
PROVIDER: S-EPMC2517130 | biostudies-literature | 2006 Jul
REPOSITORIES: biostudies-literature
Baati Rachid R Mioskowski Charles C Barma Deb D Kache Rajashaker R Falck J R JR
Organic letters 20060701 14
[reaction: see text] The combination of CrCl(2) and silyl chlorides converts aryl and conjugated aldehydes into olefinic adducts in good to excellent yields. When constrained by structural features, the intermediate vic-diol can be isolated. Available data are consistent with a novel chromium Brook rearrangement. ...[more]