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Allenyl azide cycloaddition chemistry. Synthesis of annelated indoles from 2-(allenyl)phenyl azide substrates.

ABSTRACT: [reaction: see text] Thermolysis of 2-(allenyl)phenyl azides leads to a cascade cyclization sequence furnishing both C(2)-C(3) and N-C(2) cyclopentannelated indoles.

SUBMITTER: Feldman KS

PROVIDER: S-EPMC2532842 | biostudies-literature | 2006 Jul

REPOSITORIES: biostudies-literature

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Allenyl azide cycloaddition chemistry. Synthesis of annelated indoles from 2-(allenyl)phenyl azide substrates.

Feldman Ken S KS Iyer Malliga R MR Hester D Keith DK

Organic letters 20060701 14

[reaction: see text] Thermolysis of 2-(allenyl)phenyl azides leads to a cascade cyclization sequence furnishing both C(2)-C(3) and N-C(2) cyclopentannelated indoles. ...[more]

PMID: 16805565

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