Unknown

Dataset Information

0

Remarkably mild and efficient intramolecular Friedel-Crafts cyclization catalyzed by In(III).


ABSTRACT: [structure: see text]. Indium(III) salts were found to be highly effective catalysts for the intramolecular Friedel-Crafts reaction of simple allylic bromides and arenes. In(III) salts appear to be the most general and possess unique halophilic properties as a Lewis acid for this reaction among the catalysts evaluated to date. Deactivated arenes possessing chloride, bromide, and fluoride underwent smooth reaction when activated by InCl3.

SUBMITTER: Hayashi R 

PROVIDER: S-EPMC2553353 | biostudies-literature | 2007 Mar

REPOSITORIES: biostudies-literature

altmetric image

Publications

Remarkably mild and efficient intramolecular Friedel-Crafts cyclization catalyzed by In(III).

Hayashi Ryuji R   Cook Gregory R GR  

Organic letters 20070309 7


[structure: see text]. Indium(III) salts were found to be highly effective catalysts for the intramolecular Friedel-Crafts reaction of simple allylic bromides and arenes. In(III) salts appear to be the most general and possess unique halophilic properties as a Lewis acid for this reaction among the catalysts evaluated to date. Deactivated arenes possessing chloride, bromide, and fluoride underwent smooth reaction when activated by InCl3. ...[more]

Similar Datasets

| S-EPMC8768868 | biostudies-literature
| S-EPMC4120523 | biostudies-literature
| S-EPMC10729024 | biostudies-literature
| S-EPMC9089239 | biostudies-literature
| S-EPMC6979362 | biostudies-literature
| S-EPMC7271029 | biostudies-literature
| S-EPMC8404216 | biostudies-literature
| S-EPMC6604704 | biostudies-literature
| S-EPMC9804301 | biostudies-literature
| S-EPMC6065310 | biostudies-other