Unknown

Dataset Information

0

Optimal TBHP allylic oxidation of Delta5-steroids catalyzed by dirhodium caprolactamate.


ABSTRACT: Dirhodium caprolactamate is the most efficient catalyst for the oxidation of Delta5-steroids to 7-keto-Delta5-steroids by 70% tert-butyl hydroperoxide in water (T-HYDRO). Isolated product yields range from 38 to 87%.

SUBMITTER: Choi H 

PROVIDER: S-EPMC2596589 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

altmetric image

Publications

Optimal TBHP allylic oxidation of Delta5-steroids catalyzed by dirhodium caprolactamate.

Choi Hojae H   Doyle Michael P MP  

Organic letters 20071121 26


Dirhodium caprolactamate is the most efficient catalyst for the oxidation of Delta5-steroids to 7-keto-Delta5-steroids by 70% tert-butyl hydroperoxide in water (T-HYDRO). Isolated product yields range from 38 to 87%. ...[more]

Similar Datasets

| S-EPMC5660929 | biostudies-literature
| S-EPMC2730049 | biostudies-literature
| S-EPMC2531164 | biostudies-literature
| S-EPMC5040325 | biostudies-literature
| S-EPMC2610808 | biostudies-literature
| S-EPMC2804976 | biostudies-literature
| S-EPMC3834613 | biostudies-literature
| S-EPMC3615722 | biostudies-literature
| S-EPMC5912103 | biostudies-other