Ontology highlight
ABSTRACT:
SUBMITTER: Restorp P
PROVIDER: S-EPMC2642476 | biostudies-literature | 2008 Sep
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20080813 36
A deep cavitand with an inwardly directed carboxylic acid function reacts with small aliphatic isonitriles to form N-acyl formamides inside the cavity. The unique isolation and stabilization of covalently bound guests within the structured environment of the cavitand allows for observation of the labile O-acyl isoimide intermediate using conventional spectroscopic methods. ...[more]