Ontology highlight
ABSTRACT:
SUBMITTER: Shook RL
PROVIDER: S-EPMC2647946 | biostudies-literature | 2008 Jul
REPOSITORIES: biostudies-literature
Shook Ryan L RL Gunderson William A WA Greaves John J Ziller Joseph W JW Hendrich Michael P MP Borovik A S AS
Journal of the American Chemical Society 20080621 28
The binding and activation of dioxygen by transition metal complexes is a fundamentally and practically important process in chemistry. Often the initial steps involve formation of peroxometal species that is difficult to observe because of their inherent reactivity. The interaction of dioxygen with a manganese(II) complex (1) of bis[(N'-tert-butylurealy)-N-ethyl]-(6-pivalamido-2-pyridylmethyl)amine was investigated, leading to the detection of a new intermediate that is a peroxomanganese(III) c ...[more]