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Carbon-rich supramolecular metallacycles and metallacages.

ABSTRACT: Coordination-driven self-assembly via the directional-bonding approach utilizes rigid transition metal acceptors and electron-rich donors to allow for complex, nanoscale 2D polygons and 3D polyhedra to be prepared under mild conditions and in high yields. To ensure proper rigidity and directionality, many acceptor and donor precursors contain largely carbon-rich aromatic and/or acetylenic moieties. This article introduces self-assembly as an alternative means of synthesizing carbon-rich materials and discusses the development, design, synthesis, and applications of carbon-rich supramolecular metallacycles and metallacages as well as the self-assembly of new diastereomeric carbon-rich supramolecular triangles.

SUBMITTER: Northrop BH

PROVIDER: S-EPMC2654325 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature

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Carbon-rich supramolecular metallacycles and metallacages.

Northrop Brian H BH Chercka Dennis D Stang Peter J PJ

Tetrahedron 20081201 50

Coordination-driven self-assembly via the directional-bonding approach utilizes rigid transition metal acceptors and electron-rich donors to allow for complex, nanoscale 2D polygons and 3D polyhedra to be prepared under mild conditions and in high yields. To ensure proper rigidity and directionality, many acceptor and donor precursors contain largely carbon-rich aromatic and/or acetylenic moieties. This article introduces self-assembly as an alternative means of synthesizing carbon-rich material ...[more]

PMID: 20011029

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