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Copper-free click chemistry for the in situ crosslinking of photodegradable star polymers.

ABSTRACT: Bifunctional, fluorinated cyclooctynes were used for the in situ "click" crosslinking of azide-terminated photodegradable star polymers, yielding photodegradable polymeric model networks with well-defined structures and tunable gelation times.

SUBMITTER: Johnson JA 

PROVIDER: S-EPMC2667816 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Copper-free click chemistry for the in situ crosslinking of photodegradable star polymers.

Johnson Jeremiah A JA   Baskin Jeremy M JM   Bertozzi Carolyn R CR   Koberstein Jeffrey T JT   Turro Nicholas J NJ  

Chemical communications (Cambridge, England) 20080424 26

Bifunctional, fluorinated cyclooctynes were used for the in situ "click" crosslinking of azide-terminated photodegradable star polymers, yielding photodegradable polymeric model networks with well-defined structures and tunable gelation times. ...[more]

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