Ontology highlight
ABSTRACT:
SUBMITTER: Qian H
PROVIDER: S-EPMC2682585 | biostudies-literature | 2009 Apr
REPOSITORIES: biostudies-literature
Qian Huifeng H Zhu Manzhou M Andersen Ulla N UN Jin Rongchao R
The journal of physical chemistry. A 20090401 16
It has long been a major challenge to achieve synthetic control over size and monodispersity of gold thiolate nanoclusters. Among the reported Aun thiolate clusters, Au38 has been shown to be particularly stable but was only obtained as a minor product in previous syntheses. In this work, we report a bulk solution synthetic method that permits large-scale, facile synthesis of truly monodisperse Au38 nanoclusters. This new method explores a two-phase ligand exchange process utilizing glutathione- ...[more]