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Synthesis of amidines using N-allyl ynamides. A palladium-catalyzed allyl transfer through an ynamido-pi-allyl complex.

ABSTRACT: A de novo transformation of N-allyl-N-sulfonyl ynamides to amidines is described featuring a palladium-catalyzed N-to-C allyl transfer via ynamido-palladium-pi-allyl complexes.

SUBMITTER: Zhang Y

PROVIDER: S-EPMC2683379 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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Synthesis of amidines using N-allyl ynamides. A palladium-catalyzed allyl transfer through an ynamido-pi-allyl complex.

Zhang Yu Y DeKorver Kyle A KA Lohse Andrew G AG Zhang Yan-Shi YS Huang Jian J Hsung Richard P RP

Organic letters 20090201 4

A de novo transformation of N-allyl-N-sulfonyl ynamides to amidines is described featuring a palladium-catalyzed N-to-C allyl transfer via ynamido-palladium-pi-allyl complexes. ...[more]

PMID: 19199763

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