Unknown

Dataset Information

0

Synthesis of amidines using N-allyl ynamides. A palladium-catalyzed allyl transfer through an ynamido-pi-allyl complex.

ABSTRACT: A de novo transformation of N-allyl-N-sulfonyl ynamides to amidines is described featuring a palladium-catalyzed N-to-C allyl transfer via ynamido-palladium-pi-allyl complexes.

SUBMITTER: Zhang Y 

PROVIDER: S-EPMC2683379 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Synthesis of amidines using N-allyl ynamides. A palladium-catalyzed allyl transfer through an ynamido-pi-allyl complex.

Zhang Yu Y   DeKorver Kyle A KA   Lohse Andrew G AG   Zhang Yan-Shi YS   Huang Jian J   Hsung Richard P RP  

Organic letters 20090201 4

A de novo transformation of N-allyl-N-sulfonyl ynamides to amidines is described featuring a palladium-catalyzed N-to-C allyl transfer via ynamido-palladium-pi-allyl complexes. ...[more]

Similar Datasets

Unknown An intramolecular [2 + 2] cycloaddition of ketenimines via palladium-catalyzed rearrangements of N-allyl-ynamides.
| S-EPMC3426664 | biostudies-literature
Unknown N-allyl-N-sulfonyl ynamides as synthetic precursors to amidines and vinylogous amidines. An unexpected N-to-C 1,3-sulfonyl shift in nitrile synthesis.
| S-EPMC3120114 | biostudies-literature
Unknown Synthesis of bicyclic ethers by a palladium-catalyzed oxidative cyclization-redox relay-π-allyl-Pd cyclization cascade reaction.
| S-EPMC6601619 | biostudies-literature
Unknown Palladium-Catalyzed Synthesis of Amidines via <i>tert</i>-Butyl isocyanide Insertion.
| S-EPMC6643982 | biostudies-literature
Unknown Palladium-catalyzed N-monoarylation of amidines and a one-pot synthesis of quinazoline derivatives.
| S-EPMC3485433 | biostudies-literature
Unknown Synthesis of Cyclic Enones by Allyl-Palladium-Catalyzed α,β-Dehydrogenation.
| S-EPMC7913890 | biostudies-literature
Unknown Palladium-catalyzed hydroarylation of 1,3-dienes with boronic esters via reductive formation of pi-allyl palladium intermediates under oxidative conditions.
| S-EPMC2911521 | biostudies-literature
Unknown Decarboxylative palladium(II)-catalyzed synthesis of aryl amidines from aryl carboxylic acids: development and mechanistic investigation.
| S-EPMC3935511 | biostudies-literature
Unknown Trapping Hemiacetals with Phosphono Substituted Palladium π-Allyl Complexes for the Synthesis of Substituted Cyclic Ethers.
| S-EPMC4518476 | biostudies-literature
Unknown Branched/linear selectivity in palladium-catalyzed allyl-allyl cross-couplings: The role of ligands.
| S-EPMC4531376 | biostudies-literature