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A short stereoselective synthesis of (+)-(6R,2'S)-cryptocaryalactone via ring-closing metathesis.

ABSTRACT: A short stereoselective synthesis of (+)-(6R,2'S)-cryptocaryalactone was successfully completed. Key steps included the application of Carreira's asymmetric alkynylation reaction to form a propargylic alcohol and subsequently lactone formation using the powerful ring-closing metathesis reaction.

SUBMITTER: Radha Krishna P 

PROVIDER: S-EPMC2686312 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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A short stereoselective synthesis of (+)-(6R,2'S)-cryptocaryalactone via ring-closing metathesis.

Radha Krishna Palakodety P   Lopinti Krishnarao K   Reddy K L N KL  

Beilstein journal of organic chemistry 20090424

A short stereoselective synthesis of (+)-(6R,2'S)-cryptocaryalactone was successfully completed. Key steps included the application of Carreira's asymmetric alkynylation reaction to form a propargylic alcohol and subsequently lactone formation using the powerful ring-closing metathesis reaction. ...[more]

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