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Chromium(0)-promoted [6pi + 2pi] cycloadditions of allenes with cycloheptatriene.

ABSTRACT: Photoinitiated [6pi + 2pi] cycloadditions of allenes with (eta(6)-cycloheptatriene)tricarbonylchromium(0) (1) are described. An example of asymmetric induction obtained by reaction of 1 with a chiral 1,3-disubstituted allene is also reported.

SUBMITTER: Rigby JH 

PROVIDER: S-EPMC2688831 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature

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Chromium(0)-promoted [6pi + 2pi] cycloadditions of allenes with cycloheptatriene.

Rigby James H JH   Laurent Stéphane B SB   Kamal Zeeshan Z   Heeg Mary Jane MJ  

Organic letters 20081201 24

Photoinitiated [6pi + 2pi] cycloadditions of allenes with (eta(6)-cycloheptatriene)tricarbonylchromium(0) (1) are described. An example of asymmetric induction obtained by reaction of 1 with a chiral 1,3-disubstituted allene is also reported. ...[more]

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