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Stereoselective synthesis of the C(1)-C(19) fragment of tetrafibricin.

ABSTRACT: [reaction: see text] A stereoselective synthesis of the C(1)-C(19) fragment of tetrafibricin has been accomplished via a highly diastereoselective double allylboration reaction of 6-8 and an iodonium ion promoted urethane cyclization for the installation of the C(15) alkoxy function in 3.

SUBMITTER: Lira R

PROVIDER: S-EPMC2701644 | biostudies-literature | 2007 Feb

REPOSITORIES: biostudies-literature

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Stereoselective synthesis of the C(1)-C(19) fragment of tetrafibricin.

Lira Ricardo R Roush William R WR

Organic letters 20070201 3

[reaction: see text] A stereoselective synthesis of the C(1)-C(19) fragment of tetrafibricin has been accomplished via a highly diastereoselective double allylboration reaction of 6-8 and an iodonium ion promoted urethane cyclization for the installation of the C(15) alkoxy function in 3. ...[more]

PMID: 17249805

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