Unknown

Dataset Information

0

New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand: Electrochemical and Photophysical Insights.

ABSTRACT: An efficient synthetic access to new cationic porphyrin-bipyridine iridium(III) bis-cyclometalated complexes was developed. These porphyrins bearing arylbipyridine moieties at β-pyrrolic positions coordinated with iridium(III), and the corresponding Zn(II) porphyrin complexes were spectroscopically, electrochemically, and electronically characterized. The features displayed by the new cyclometalated porphyrin-bipyridine iridium(III) complexes, namely photoinduced electron transfer process (PET), and a remarkable efficiency to generate 1O2, allowing us to envisage new challenges and opportunities for their applications in several fields, such as photo(catalysis) and photodynamic therapies.

SUBMITTER: Moura NMM 

PROVIDER: S-EPMC9319630 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand: Electrochemical and Photophysical Insights.

Moura Nuno M M NMM   Serra Vanda Vaz VV   Bastos Alexandre A   Biazotto Juliana C JC   Castro Kelly A D F KADF   Faustino Maria Amparo F MAF   Lodeiro Carlos C   da Silva Roberto S RS   Neves Maria da Graça P M S MDGPMS  

International journal of molecular sciences 20220709 14

An efficient synthetic access to new cationic porphyrin-bipyridine iridium(III) bis-cyclometalated complexes was developed. These porphyrins bearing arylbipyridine moieties at β-pyrrolic positions coordinated with iridium(III), and the corresponding Zn(II) porphyrin complexes were spectroscopically, electrochemically, and electronically characterized. The features displayed by the new cyclometalated porphyrin-bipyridine iridium(III) complexes, namely photoinduced electron transfer process (PET),  ...[more]

Similar Datasets

Unknown Stereoselective Synthesis of Cyclometalated Iridium (III) Complexes: Characterization and Photophysical Properties.
| S-EPMC2711639 | biostudies-literature
Unknown Effects of Ancillary Ligands on Deep Red to Near-Infrared Cyclometalated Iridium Complexes.
| S-EPMC9954257 | biostudies-literature
Unknown Spectroscopic, Electrochemical and DFT Studies of Phosphorescent Homoleptic Cyclometalated Iridium(III) Complexes Based on Substituted 4-Fluorophenylvinyl- and 4-Methoxyphenylvinylquinolines.
| S-EPMC5666912 | biostudies-literature
Unknown pH-Responsive N^C-Cyclometalated Iridium(III) Complexes: Synthesis, Photophysical Properties, Computational Results, and Bioimaging Application.
| S-EPMC8747057 | biostudies-literature
Unknown Photophysical and Photobiological Properties of Dinuclear Iridium(III) Bis-tridentate Complexes.
| S-EPMC6337720 | biostudies-literature
Unknown Divergent Approach for <i>Tris</i>-Heteroleptic Cyclometalated Iridium Complexes Using Triisopropylsilylethynyl-Substituted Synthons.
| S-EPMC9477230 | biostudies-literature
Unknown Bis-Cyclometalated Indazole and Benzimidazole Chiral-at-Iridium Complexes: Synthesis and Asymmetric Catalysis.
| S-EPMC8037582 | biostudies-literature
Unknown Oncosis-inducing cyclometalated iridium(iii) complexes.
| S-EPMC6000986 | biostudies-literature
Unknown Bis-cyclometalated iridium(iii) complexes with terpyridine analogues: syntheses, structures, spectroscopy and computational studies.
| S-EPMC9044569 | biostudies-literature
Unknown Luminescent Anionic Cyclometalated Organoplatinum (II) Complexes with Terminal and Bridging Cyanide Ligand: Structural and Photophysical Properties.
| S-EPMC9890487 | biostudies-literature