Cyanoximes as effective and selective co-crystallizing agents.
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ABSTRACT:
SUBMITTER: Aakeroy CB
PROVIDER: S-EPMC2748950 | biostudies-literature | 2009 Jan
REPOSITORIES: biostudies-literature
Publications
Cyanoximes as effective and selective co-crystallizing agents.
Aakeröy Christer B CB Salmon Debra J DJ Smith Michelle M MM Desper John J
CrystEngComm 20090101 3
The ability of cyanoxime-based synthons to act as versatile synthetic tools for the construction of co-crystals is demonstrated through the preparation and structural characterization of seven co-crystals. Cyanoximes can bind effectively to both five-membered and six-membered N-heterocyclic hydrogen-bond acceptors, and they also display selectivity towards the best acceptor (as determined using semi-empirical AM1 calculations) in ditopic compounds. ...[more]
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