Unknown

Dataset Information

0

A stereoselective synthesis of the bromopyrrole natural product (-)-agelastatin A.


ABSTRACT: Weaving an intricate web: A stereoselective synthesis of (-)-agelastatin A has been developed, which requires 11 steps from commercially available starting material. The application of a Rh-catalyzed intramolecular olefin aziridination reaction and the subsequent manipulation of the resulting tricyclic intermediate (see scheme) punctuate this study.

SUBMITTER: Wehn PM 

PROVIDER: S-EPMC2791535 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

altmetric image

Publications

A stereoselective synthesis of the bromopyrrole natural product (-)-agelastatin A.

Wehn Paul M PM   Du Bois J J  

Angewandte Chemie (International ed. in English) 20090101 21


Weaving an intricate web: A stereoselective synthesis of (-)-agelastatin A has been developed, which requires 11 steps from commercially available starting material. The application of a Rh-catalyzed intramolecular olefin aziridination reaction and the subsequent manipulation of the resulting tricyclic intermediate (see scheme) punctuate this study. ...[more]

Similar Datasets

| S-EPMC6595966 | biostudies-literature
2017-04-17 | GSE85619 | GEO
| S-EPMC5562292 | biostudies-literature
| S-EPMC5571482 | biostudies-literature
| S-EPMC8596708 | biostudies-literature
| S-EPMC8949637 | biostudies-literature
| S-EPMC3016719 | biostudies-literature
| S-EPMC3815442 | biostudies-literature
| S-EPMC6256351 | biostudies-literature
| S-EPMC10005508 | biostudies-literature