Air/Water-Stable Tridentate NHC-Pd Complex; Catalytic C-H Activation of Hydrocarbons via H/D Exchange Process in D(2)O.
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ABSTRACT:
SUBMITTER: Lee JH
PROVIDER: S-EPMC2835316 | biostudies-literature | 2009 Mar
REPOSITORIES: biostudies-literature
Publications
Air/Water-Stable Tridentate NHC-Pd Complex; Catalytic C-H Activation of Hydrocarbons via H/D Exchange Process in D(2)O.
Lee Joo Ho JH Yoo Kyung Soo KS Park Chan Pil CP Olsen Janet M JM Sakaguchi Satoshi S Surya Prakash G K GK Mathew Thomas T Jung Kyung Woon KW
Advanced synthesis & catalysis 20090301 4
While developing novel catalysts for carbon-carbon or carbon-heteroatom coupling (N, O, or F), we were able to introduce tridentate NHC-amidate-alkoxide palladium(II) complexes. In aqueous solution, these NHC-Pd(II) complexes showed high ability for C-H activation of various hydrocarbons (cyclohexane, cyclopentane, dimethyl ether, THF, acetone, and toluene) under mild conditions. ...[more]
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