Ontology highlight
ABSTRACT:
SUBMITTER: Ball ND
PROVIDER: S-EPMC2855696 | biostudies-literature | 2010 Jan
REPOSITORIES: biostudies-literature
Dalton transactions (Cambridge, England : 2003) 20091126 2
This article describes the synthesis, characterization, and reactivity of palladium(II) fluoride complexes containing sp(2) and sp(3) nitrogen-containing supporting ligands. Both cis and trans complexes of general structure (N)(N')Pd(II)(R)(F) (R = Ar or CH(3)) as well as cis-(N)(2)Pd(II)(F)(2) are reported. Crystallographic characterization of these molecules has allowed structural comparisons to related phosphine-ligated species. Furthermore, these studies have revealed that nitrogen-donor lig ...[more]