Ontology highlight
ABSTRACT:
SUBMITTER: Sui B
PROVIDER: S-EPMC2871111 | biostudies-literature | 2010 May
REPOSITORIES: biostudies-literature
The Journal of organic chemistry 20100501 9
Two different mixture synthesis routes have been used to make the four stereoisomers of petrocortyne A. A first quick and dirty route provided a mixture of the four isomers in nonselective fashion. Mosher and 2-naphthylmethoxyacetic acid (NMA) ester methods were developed to identify the components, and the mixture was partially resolved on analytical chiral HPLC to give the two pure enantiomers of petrocortyne A and the racemate of its diastereomer. A second fluorous mixture synthesis produced ...[more]