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Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis.

ABSTRACT: Chiral isotactic polystyrenes induce the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, affording the enantiomerically enriched pyrimidyl alkanol with the corresponding absolute configuration to that of cryptochiral polystyrenes in conjunction with asymmetric autocatalysis.

SUBMITTER: Kawasaki T

PROVIDER: S-EPMC2898645 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis.

Kawasaki Tsuneomi T Hohberger Christiane C Araki Yuko Y Hatase Kunihiko K Beckerle Klaus K Okuda Jun J Soai Kenso K

Chemical communications (Cambridge, England) 20090821 37

Chiral isotactic polystyrenes induce the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, affording the enantiomerically enriched pyrimidyl alkanol with the corresponding absolute configuration to that of cryptochiral polystyrenes in conjunction with asymmetric autocatalysis. ...[more]

PMID: 19753377

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