Ontology highlight
ABSTRACT:
SUBMITTER: Werner EW
PROVIDER: S-EPMC2908953 | biostudies-literature | 2010 Jun
REPOSITORIES: biostudies-literature
Werner Erik W EW Urkalan Kaveri B KB Sigman Matthew S MS
Organic letters 20100601 12
Evaluation of the scope of a Pd(II)-catalyzed oxidative 1,1-diarylation reaction of terminal olefins using aryl stannanes is reported. The reaction is shown to be tolerant of functionality commonly encountered in organic synthesis; however, the reaction outcome was found to be dependent on the nature of the aryl stannane used. A mechanistic rationale for the observation of this influence is provided. ...[more]