Strained to the limit: when a cyclobutyl moiety becomes a thermodynamic sink in a protolytic ring-opening of photogenerated oxetanes.
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ABSTRACT:
SUBMITTER: Valiulin RA
PROVIDER: S-EPMC2912957 | biostudies-literature | 2010 Aug
REPOSITORIES: biostudies-literature
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Strained to the limit: when a cyclobutyl moiety becomes a thermodynamic sink in a protolytic ring-opening of photogenerated oxetanes.
Valiulin Roman A RA Arisco Teresa M TM Kutateladze Andrei G AG
Organic letters 20100801 15
Strained polycyclic oxetanes generated photochemically from the Diels-Alder adducts of cyclic dienes and enones undergo deep skeletal rearrangements under protolytic ring-opening conditions offering expeditious access to chlorohydrins and other products of unique skeletal topology. ...[more]
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