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(Z)-N-[3-(2-Methoxy-phen-yl)-4-phenyl-2,3-dihydro-thia-zol-2-yl-idene]-4-methyl-benzamide.

ABSTRACT: Geometric parameters of the title compound, C(24)H(20)N(2)O(2)S, are in the usual ranges. The central heterocycle makes dihedral angles of 41.29?(4) and 72.94?(5)° with the phenyl ring and the methoxy-phenyl ring, respectively.

SUBMITTER: Saeed A

PROVIDER: S-EPMC2915025 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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(Z)-N-[3-(2-Methoxy-phen-yl)-4-phenyl-2,3-dihydro-thia-zol-2-yl-idene]-4-methyl-benzamide.

Saeed Aamer A Zaman Sabah S Bolte Michael M

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

Geometric parameters of the title compound, C(24)H(20)N(2)O(2)S, are in the usual ranges. The central heterocycle makes dihedral angles of 41.29 (4) and 72.94 (5)° with the phenyl ring and the methoxy-phenyl ring, respectively. ...[more]

PMID: 21200944

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(Z)-N-[3-(2-Methoxy-phen-yl)-4-phenyl-2,3-dihydro-thia-zol-2-yl-idene]-2-methyl-benzamide.

Project description:In the title mol-ecule, C(24)H(20)N(2)O(2)S, the thia-zole and amide groups are essentially coplanar. The thia-zole ring forms dihedral angles of 61.62?(4) and 26.75?(5)° with the benzene rings of the methoxy-phenyl and methyl-phenyl groups, respectively, and 33.69?(6)° with the phenyl ring. The crystal packing is stabilized by inter-molecular C-H?O hydrogen bonds, forming a three-dimensional network.

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(Z)-2-[Meth-oxy(phen-yl)methyl-idene]-3,4,5-trimethyl-2,3-dihydro-1,3-thia-zole.

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Poly[aqua-[?-4-(4-chloro-phen-yl)-2-thioxo-2,3-dihydro-thia-zol-3-olato]-sodium(I)].

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Crystal structures of <i>N</i>-[(4-phenyl-thia-zol-2-yl)carbamo-thio-yl]benzamide and <i>N</i>-{[4-(4-bromo-phen-yl)thia-zol-2-yl]carbamo-thio-yl}benzamide from synchrotron X-ray diffraction.

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(Z)-2-(5-Acetyl-4-methyl-3-phenyl-2,3-dihydro-1,3-thia-zol-2-yl-idene)-3-(3-methyl-1-benzofuran-2-yl)-3-oxo-propane-nitrile.

Project description:In the title compound, C(24)H(18)N(2)O(3)S, the benzofuran ring system (r.m.s. deviation = 0.010?Å) forms dihedral angles of 83.13?(17) and 8.92?(14)° with the benzene and thia-zole rings, respectively. The dihedral angle between the benzene and thia-zole rings is 84.51?(19)°. The mol-ecular structure features an intra-molecular C-H?O hydrogen bond, which closes an S(6) ring. There are no inter-molecular hydrogen bonds observed in this structure.

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Crystal structure of 4-((1E)-1-{(2Z)-2-[4-(4-bromo-phen-yl)-3-phenyl-2,3-di-hydro-1,3-thia-zol-2-yl-idene]hydrazin-1-yl-idene}eth-yl)phenol hemihydrate.

Project description:In the title compound, C23H18BrN3OS·0.5H2O, the bromo-phenyl, phenyl and phenol rings make dihedral angles of 46.5?(1), 66.78?(8) and 15.4?(2)°, respectively, with the mean squares plane of the thia-zol-idene ring. In the crystal, the lattice water mol-ecule is hydrogen bonded to the phenol group and makes a weaker O-H?N connection to an inversion-related mol-ecule, forming a ring while weak pairwise C-H?S inter-actions involving inversion-related mol-ecules form a second ring. Both these motifs result in the formation of two-dimensional networks lying parallel to (10-1).

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N-(1,3-Thia-zol-2-yl)benzamide.

Project description:The title compound, C(10)H(8)N(2)OS, features a nonplanar mol-ecule [dihedral angle between the two aromatic rings = 43.6?(1)°]. Two mol-ecules are linked by N-H?N hydrogen bonds about a centre of inversion, giving rise to a hydrogen-bonded dimer.

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2-(4-Fluoro-phen-yl)-N-{4-[6-(4-fluoro-phen-yl)-2,3-dihydro-imidazo[2,1-b][1,3]thia-zol-5-yl]pyridin-2-yl}acetamide.

Project description:In the crystal structure of the title compound, C(24)H(18)F(2)N(4)OS, the imidazole system makes dihedral angles of 34.3?(1) and 43.9?(1)°, respectively, with the directly attached 4-fluoro-phenyl and pyridine rings. The crystal structure is stabilized by inter-molecular N-H?N hydrogen bonding and by an intra-molecular C-H?O hydrogen inter-action. The F atom of the 2-(4-fluoro-phen-yl) group is disordered over two positions with site-occupancy factors of 0.75 and 0.25.

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N-(2,3-Dihydro-1,3-thia-zol-2-yl-idene)-4-[(2-hydroxy-benzyl-idene)amino]benzene-sulfonamide.

Project description:The title compound, C(16)H(13)N(3)O(3)S(2), was prepared by reaction of salicylaldehyde and sulfathia-zole in methanol. The dihedral angle between the central benzene ring and the thia-zole ring is 85.2?(2)° and that between the two benzene rings is 17.9?(2)°. An intra-molecular O-H?N hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are held together by inter-molecular N-H?N and C-H?O hydrogen bonds, forming a two-dimensional network parallel to the bc plane.

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