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7,11,15,28-Tetra-methyl-1,21,23,25-tetra-kis(2-phenyl-ethyl)resorcin[4]arene ethyl acetate clathrate.

ABSTRACT: The title compound, C(68)H(64)O(8)·C(4)H(8)O(2), is a new resorcin-[4]arene cavitand synthetic precursor, obtained by alkyl-ation of a previously reported resorcin[4]arene. The additional alkyl bridges significantly rigidify the structure and enforce a 'bowl' shape on the mol-ecular cavity. In the crystal structure, the mol-ecule lies on a crystallographic mirror plane, and a single ethyl acetate mol-ecule (also lying on the mirror plane) is present within the compound cavity, illustrating the host capabilities of the mol-ecule.

SUBMITTER: Mc Kay MG

PROVIDER: S-EPMC2915052 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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7,11,15,28-Tetra-methyl-1,21,23,25-tetra-kis(2-phenyl-ethyl)resorcin[4]arene ethyl acetate clathrate.

Mc Kay Michael G MG Friedrich Holger B HB Maguire Glenn E M GE

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

The title compound, C(68)H(64)O(8)·C(4)H(8)O(2), is a new resorcin-[4]arene cavitand synthetic precursor, obtained by alkyl-ation of a previously reported resorcin[4]arene. The additional alkyl bridges significantly rigidify the structure and enforce a 'bowl' shape on the mol-ecular cavity. In the crystal structure, the mol-ecule lies on a crystallographic mirror plane, and a single ethyl acetate mol-ecule (also lying on the mirror plane) is present within the compound cavity, illustrating the h ...[more]

PMID: 21200974

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7,11,15,28-Tetra-kis[(2-formyl-phen-oxy)methyl]-1,21,23,25-tetra-methyl-resorcin[4]arene cavitand ethyl acetate clathrate at 173 K.

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