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Monoclinic polymorph of poly[[di-?-aqua-triaquadi-?-oxalato-barium(II)-copper(II)] monohydrate].


ABSTRACT: A monoclinic polymorph of the title compound, {[BaCu(C(2)O(4))(2)(H(2)O)(5)]·H(2)O}(n), is reported. The structure is best described as a coordination polymer where the Cu(II) and Ba(II) centers are coordinated by five and nine O atoms, respectively, in capped quadratic antiprismatic and tetragonal pyramidal geometries. The polymerization arises due to the presence of bridging mono- and bidentate oxalate ligands as well as bridging water mol-ecules. The crystal structure is consolidated by a three-dimensional network of hydrogen bonding.

SUBMITTER: Nenwa J 

PROVIDER: S-EPMC2915069 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)-copper(II)] monohydrate].

Nenwa Justin J   Belombe Michel M MM   Fokwa Boniface P T BP   Dronskowski Richard R  

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1


A monoclinic polymorph of the title compound, {[BaCu(C(2)O(4))(2)(H(2)O)(5)]·H(2)O}(n), is reported. The structure is best described as a coordination polymer where the Cu(II) and Ba(II) centers are coordinated by five and nine O atoms, respectively, in capped quadratic antiprismatic and tetragonal pyramidal geometries. The polymerization arises due to the presence of bridging mono- and bidentate oxalate ligands as well as bridging water mol-ecules. The crystal structure is consolidated by a thr  ...[more]

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