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Poly[[μ-1,4-anhydro-erythritolato-di-μ-aqua-sodium(I)] monohydrate].

ABSTRACT: In the title compound, {[Na(C(4)H(7)O(3))(H(2)O)(2)]·H(2)O}(n), the sodium ion is octa-hedrally coordinated by two bridging 1,4-anhydro-erythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional anti-tactical polymeric chains along [010]. One of the exocyclic O atoms of the anhydro-erythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated.

SUBMITTER: Kerscher T

PROVIDER: S-EPMC2959930 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Poly[[μ-1,4-anhydro-erythritolato-di-μ-aqua-sodium(I)] monohydrate].

Kerscher Tobias T Zeller Patrick P Mayer Peter P Klüfers Peter P

Acta crystallographica. Section E, Structure reports online 20081129 Pt 12

In the title compound, {[Na(C(4)H(7)O(3))(H(2)O)(2)]·H(2)O}(n), the sodium ion is octa-hedrally coordinated by two bridging 1,4-anhydro-erythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional anti-tactical polymeric chains along [010]. One of the exocyclic O atoms of the anhydro-erythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated. ...[more]

PMID: 21581226

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