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N'-Ferrocenyl-2-hydroxy-benzohydrazide.

ABSTRACT: The title complex, [Fe(C(5)H(5))(C(13)H(11)N(2)O(3))], was prepared via self-assembly using ferrocenyl hydrazide and ethyl salicylate. The compound is potentially a tridentate ferrocene-based ligand. The conformation of the mol-ecule allows the formation of an intra-molecular N-H?O hydrogen bond involving the hydroxyl group. The CONHNHCO unit and the rings bonded to it are nearly coplanar. The crystal structure is stabilized by inter-molecular O-H?O(carbon-yl) and N-H?O(carbon-yl) hydrogen bonds.

SUBMITTER: Xu Y

PROVIDER: S-EPMC2915112 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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N'-Ferrocenyl-2-hydroxy-benzohydrazide.

Xu Ying Y Chen Chun-Ling CL Zhou Jing J Li Ming-Xue MX

Acta crystallographica. Section E, Structure reports online 20071212 Pt 1

The title complex, [Fe(C(5)H(5))(C(13)H(11)N(2)O(3))], was prepared via self-assembly using ferrocenyl hydrazide and ethyl salicylate. The compound is potentially a tridentate ferrocene-based ligand. The conformation of the mol-ecule allows the formation of an intra-molecular N-H⋯O hydrogen bond involving the hydroxyl group. The CONHNHCO unit and the rings bonded to it are nearly coplanar. The crystal structure is stabilized by inter-molecular O-H⋯O(carbon-yl) and N-H⋯O(carbon-yl) hydrogen bonds ...[more]

PMID: 21200525

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