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1,3-Bis(2,6-diisopropyl-anilino)-1-phenyl-butyl-ium hexa-fluorido-phosphate.

ABSTRACT: The cation of the title salt, C(34)H(45)N(2) (+)·PF(6) (-), is a protonated form of an unsymmetrical overcrowded ?-imino-amine. The observed bond lengths [C-N = 1.326?(4)-1.341?(4)?Å and C-C = 1.383?(4)-1.391?(4)?Å] suggest significant delocalization within the ? system of the N C C C N backbone.

SUBMITTER: Elmkacher NB

PROVIDER: S-EPMC2915305 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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1,3-Bis(2,6-diisopropyl-anilino)-1-phenyl-butyl-ium hexa-fluorido-phosphate.

Elmkacher Najoua Belhaj Mbarek NB Rzaigui Mohamed M Bouachir Faouzi F

Acta crystallographica. Section E, Structure reports online 20071212 Pt 1

The cation of the title salt, C(34)H(45)N(2) (+)·PF(6) (-), is a protonated form of an unsymmetrical overcrowded β-imino-amine. The observed bond lengths [C-N = 1.326 (4)-1.341 (4) Å and C-C = 1.383 (4)-1.391 (4) Å] suggest significant delocalization within the π system of the N C C C N backbone. ...[more]

PMID: 21200813

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