Unknown

Dataset Information

0

1,3-Bis(2,6-diisopropyl-anilino)-1-phenyl-butyl-ium hexa-fluorido-phosphate.

ABSTRACT: The cation of the title salt, C(34)H(45)N(2) (+)·PF(6) (-), is a protonated form of an unsymmetrical overcrowded ?-imino-amine. The observed bond lengths [C-N = 1.326?(4)-1.341?(4)?Å and C-C = 1.383?(4)-1.391?(4)?Å] suggest significant delocalization within the ? system of the N C C C N backbone.

SUBMITTER: Elmkacher NB 

PROVIDER: S-EPMC2915305 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

1,3-Bis(2,6-diisopropyl-anilino)-1-phenyl-butyl-ium hexa-fluorido-phosphate.

Elmkacher Najoua Belhaj Mbarek NB   Rzaigui Mohamed M   Bouachir Faouzi F  

Acta crystallographica. Section E, Structure reports online 20071212 Pt 1

The cation of the title salt, C(34)H(45)N(2) (+)·PF(6) (-), is a protonated form of an unsymmetrical overcrowded β-imino-amine. The observed bond lengths [C-N = 1.326 (4)-1.341 (4) Å and C-C = 1.383 (4)-1.391 (4) Å] suggest significant delocalization within the π system of the N C C C N backbone. ...[more]

Similar Datasets

Unknown 3,3'-Dicyclo-pentyl-1,1'-(1,3-phenyl-enedimethyl-ene)dibenzimidazol-1-ium bis-(hexa-fluoro-phosphate).
| S-EPMC3379432 | biostudies-literature
Unknown 1,3-Bis(2,6-diisopropyl-phen-yl)-4,5-dihydro-1H-imidazol-3-ium triiodide.
| S-EPMC3011707 | biostudies-literature
Unknown Bis{2-[(diisopropyl-phosphan-yl)amino]-pyridine-?N,P}copper(I) hexa-fluorido-phosphate.
| S-EPMC3006723 | biostudies-literature
Unknown 1-(Ferrocen-1-ylmeth-yl)-3-methyl-imidazol-3-ium hexa-fluorido-phosphate.
| S-EPMC3343779 | biostudies-literature
Unknown 1,3-Bis(2,6-diisopropyl-phen-yl)-1H-imidazol-3-ium bromide dichloro-methane disolvate.
| S-EPMC3379414 | biostudies-literature
Unknown 1,3-Bis(2,6-diisopropyl-phen-yl)-1H-imidazol-3-ium chloride dichloro-methane disolvate.
| S-EPMC3379413 | biostudies-literature
Unknown {2,6-Bis[(2,6-diisopropyl-phosphan-yl)-oxy]-4-fluoro-phenyl-?(3)P,C(1),P'}(1H-pyrazole-?N(2))nickel(II) hexa-fluoro-phosphate.
| S-EPMC3470159 | biostudies-literature
Unknown N-(2,6-Dimethyl-anilino)-5,6-dihydro-4H-1,3-thia-zin-3-ium chloride monohydrate.
| S-EPMC2961393 | biostudies-literature
Unknown 1,3-Bis(2,6-diisopropyl-phen-yl)imidazolidinium tetra-phenyl-borate dichloro-methane disolvate.
| S-EPMC3007462 | biostudies-literature
Unknown (E)-4-tert-Butyl-2-(2,6-diisopropyl-phenyl-imino-meth-yl)-6-(morpholinometh-yl)phenol.
| S-EPMC2960942 | biostudies-literature