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Triethyl-ammonium N'-(benzyl-sulfanylthio-carbonyl)-2-hydroxy-benzohydrazidate.


ABSTRACT: In the title compound, C(6)H(16)N(+)·C(15)H(13)N(2)O(2)S(2) (-), the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81?(2)°. The mol-ecular conformation is stabilized by intra-molecular O-H?O and N-H?S hydrogen bonds, while inter-molecular N-H?O, N-H?N and weak C-H?O inter-actions help to stabilize the crystal structure.

SUBMITTER: Singh M 

PROVIDER: S-EPMC2915380 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Triethyl-ammonium N'-(benzyl-sulfanylthio-carbonyl)-2-hydroxy-benzohydrazidate.

Singh Mamata M   Srivastava Ajay K AK   Singh N K NK   Shrivastav Anuraag A   Sharma R K RK  

Acta crystallographica. Section E, Structure reports online 20071221 Pt 1


In the title compound, C(6)H(16)N(+)·C(15)H(13)N(2)O(2)S(2) (-), the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81 (2)°. The mol-ecular conformation is stabilized by intra-molecular O-H⋯O and N-H⋯S hydrogen bonds, while inter-molecular N-H⋯O, N-H⋯N and weak C-H⋯O inter-actions help to stabilize the crystal structure. ...[more]

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