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(E)-Methyl 2-[(4-nitro-phen-yl)-hydrazono]-propanoate.

ABSTRACT: The title compound, C(10)H(11)N(3)O(4), is a condensation product of 4-nitro-phenyl-hydrazine and methyl pyruvate. The complete mol-ecule except for the methyl groups can be considered as a conjugated ? system. All non-H atoms are approximately coplanar (r.m.s. deviation 0.117?Å). The crystal packing involves an N-H?O hydrogen bond and a ?-? inter-action between the aromatic rings, with a centroid-centroid distance of 3.617?Å.

SUBMITTER: Yu HY

PROVIDER: S-EPMC2915385 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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(E)-Methyl 2-[(4-nitro-phen-yl)-hydrazono]-propanoate.

Yu Hai-Yang HY Fang Xin X Cao Ming-Lei ML Zhang Yan-Jun YJ Wang Jun-Dong JD

Acta crystallographica. Section E, Structure reports online 20071221 Pt 1

The title compound, C(10)H(11)N(3)O(4), is a condensation product of 4-nitro-phenyl-hydrazine and methyl pyruvate. The complete mol-ecule except for the methyl groups can be considered as a conjugated π system. All non-H atoms are approximately coplanar (r.m.s. deviation 0.117 Å). The crystal packing involves an N-H⋯O hydrogen bond and a π-π inter-action between the aromatic rings, with a centroid-centroid distance of 3.617 Å. ...[more]

PMID: 21200906

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