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Methyl 2-[2-(6-chloro-pyrimidin-4-yl-oxy)phen-yl]-3,3-dimethoxy-propanoate.

ABSTRACT: In the title compound, C(16)H(17)ClN(2)O(5), the dihedral angle between the aromatic rings is 77.36?(4)°. An intra-molecular C-H?O inter-action results in the formation of a planar [r.m.s. deviation = 0.103 (2) Å] five-membered ring, which is oriented at a dihedral angle of 4.84?(4)° with respect to the adjacent benzene ring. In the crystal structure, weak intermolecular C-H?? inter-actions are found.

SUBMITTER: Sheng C

PROVIDER: S-EPMC2970010 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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Methyl 2-[2-(6-chloro-pyrimidin-4-yl-oxy)phen-yl]-3,3-dimethoxy-propanoate.

Sheng Chao C Xu Qing-Bing QB Liu Yuan-Yuan YY Zhu Hong-Jun HJ

Acta crystallographica. Section E, Structure reports online 20090808 Pt 9

In the title compound, C(16)H(17)ClN(2)O(5), the dihedral angle between the aromatic rings is 77.36 (4)°. An intra-molecular C-H⋯O inter-action results in the formation of a planar [r.m.s. deviation = 0.103 (2) Å] five-membered ring, which is oriented at a dihedral angle of 4.84 (4)° with respect to the adjacent benzene ring. In the crystal structure, weak intermolecular C-H⋯π inter-actions are found. ...[more]

PMID: 21577532

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