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ABSTRACT:
SUBMITTER: Fabre B
PROVIDER: S-EPMC2919152 | biostudies-literature | 2010 Mar
REPOSITORIES: biostudies-literature
ACS applied materials & interfaces 20100301 3
New cobalt(III) bis(dicarbollide) complexes covalently linked to two 2-oligothienyl units have been synthesized and electropolymerized in acetonitrile electrolyte in order to produce the corresponding polythiophene films containing in-chain metallic centers. The polymer films electrogenerated from the bithienyl (4b) and terthienyl (4c) derivatives display redox processes attributed to the Co(III)/Co(II) couple at ca. -1.1 V vs SCE and to the p-doping/undoping of the expected quaterthienyl and se ...[more]