Browse
Submit Data
Databases
API
Help

Dataset Information

24 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

{4,4'-Dimeth-oxy-2,2'-[ethyl-enedioxy-bis(nitrilo-methyl-idyne)]diphenolato}copper(II).

ABSTRACT: The title complex, [Cu(C(18)H(18)N(2)O(6))], was synthesized by the reaction of copper(II) acetate mono-hydrate with the ligand 4,4'-dimeth-oxy-2,2'-[ethyl-enedioxy-bis(nitrilo-methyl-idyne)]diphenol (H(2)L). The Cu atom is coordinated by two O atoms and two N atoms of the L(2-) unit. A bridged dimer is formed through inter-molecular Cu⋯O inter-actions [Cu⋯O = 1.9408 (15) Å], creating a distorted square-pyramidal geometry about the Cu atoms.

SUBMITTER: Sun YX

PROVIDER: S-EPMC2924182 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Aqua-{4,4'-dibromo-6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}copper(II).

Project description:The title complex, [Cu(C(18)H(16)Br(2)N(2)O(4))(H(2)O)], lies on a crystallographic mirror plane with the Cu(II) ion coordinated by two N atoms and two O atoms of a tetra-dentate Schiff base ligand and one O atom from a water ligand in a slightly distorted square-pyramidal environment. The mirror plane, which coincides with the Cu-O(water) bond, imposes disorder of the atoms of the ethyl-ene group. In the crystal structure, inter-molecular O-H?O hydrogen bonds link complex mol-ecules into extended chains along [100].

| S-EPMC2972126 | biostudies-literature

{4,4'-Dimeth-oxy-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}nickel(II).

Project description:In the title complex, [Ni(C(21)H(24)N(2)O(4))], the Ni(II) ion has a slightly distorted square-planar geometry, coordinated by the two N and two O atoms of a new tetra-dentate Schiff base ligand. The dihedral angle between the planes of the two NiNC(3)O chelate rings is 14.37?(12)°.

| S-EPMC2969458 | biostudies-literature

Aqua{6,6'-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}copper(II).

Project description:In the asymmetric unit of the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)], there are two independent mononuclear Cu(II) complexes. The coordination environment of each Cu(II) ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water mol-ecule occupying the apical position. Neighbouring complexes are connected via O-H?O hydrogen bonds between the water mol-ecule and the meth-oxy group, forming a chain structure along the a axis. The propyl-ene groups of the two independent complexes are disordered over two positions with site occupancies of 0.361?(7):0.639?(7) and 0.224?(8):0.776?(8). The crystal under investigation was a partial inversion twin.

| S-EPMC2971379 | biostudies-literature

{4,4'-Dimeth-oxy-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}copper(II) monohydrate.

Project description:The asymmetric unit of the title compound, [Cu(C(21)H(24)N(2)O(4))]·H(2)O, comprises half of a Schiff base complex and a water mol-ecule. The Cu(II) atom, water mol-ecule and one C atom of the central propyl-ene segment are located on a twofold rotation axis. The geometry around the Cu(II) atom is distorted square-planar, supported by the N(2)O(2) donor atoms of the coordinating ligand. The dihedral angle between the symmetry-related benzene rings is 42.56?(19)°. In the crystal, O-H?O hydrogen bonds involving the water mol-ecule make an R(2) (1)(6) ring motif. Complex mol-ecules are linked into a chain along the c axis via C-H?O inter-actions.

| S-EPMC3470142 | biostudies-literature

4,4'-Dimeth-oxy-2,2'-[(butane-1,4-diyldi-oxy)bis-(nitrilo-methyl-idyne)]diphenol.

Project description:The title Schiff base bis-oxime compound, C(20)H(24)N(2)O(6), lies across an inversion centre and adopts an E configuration with respect to the C=N bond. In the mol-ecule, the oxime group is roughly coplanar with the benzene ring, forming a dihedral angle of 1.77?(2)°. An intra-molecular O-H?N hydrogen bond forms a six-membered ring with an S(6) motif. Weak inter-molecular C-H?O hydrogen bonding is present in the crystal structure.

| S-EPMC3009145 | biostudies-literature

{4,4'-Dibromo-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}copper(II).

Project description:In the title compound, [Cu(C(16)H(12)Br(2)N(2)O(2))], the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by two O and two N atoms of the tetra-dentate dianionic 4,4'-dibromo-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphen-olate Schiff base ligand.

| S-EPMC2977491 | biostudies-literature

4,4'-Dimethyl-1,1'-[ethyl-enedioxy-bis(nitrilo-methyl-idyne)]dibenzene.

Project description:The Schiff base, C(18)H(20)N(2)O(2), which lies about an inversion centre, adopts a linear conformation. The mol-ecules are packed by C-H⋯π inter-actions, forming a two-dimensional supra-molecular network.

| S-EPMC2969725 | biostudies-literature

Aqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}nickel(II).

Project description:The title complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], lies on a mirror plane with the Ni(II) ion coordinated by two N and two O atoms of a tetra-dentate Schiff base ligand and one water O atom in a distorted square-pyramidal enviroment. The -CH(2)-CH(2)- group of the ligand is disordered equally over two sites about the mirror plane. The dihedral angle between the mean planes of the two symmetry-related chelate rings is 37.16?(6)°. In the crystal structure, inter-molecular O-H?O hydrogen bonds link complex mol-ecules into one-dimensional chains along [100] and these chains are linked, in turn, by very weak inter-molecular C-H?O hydrogen bonds into a two-dimensional network.

| S-EPMC2970327 | biostudies-literature

{6,6'-Dieth-oxy-2,2'-[ethyl-enebis(nitrilo-methyl-idyne)]diphenolato}nickel(II) monohydrate.

Project description:In the title compound, [Ni(C(20)H(22)N(2)O(4))]·H(2)O, the Ni(II) ion and the water mol-ecule are located on a twofold rotation axis. The Ni ion is coordinated by two N [Ni-N = 1.8462 (18) Å] and two O [Ni-O = 1.8645 (14) Å] atoms in a distorted square-planar geometry. The water mol-ecule and the Ni complex mol-ecule are paired via O-H⋯O hydrogen bonds.

| S-EPMC2959910 | biostudies-literature

Bis{?-4,4'-dimeth-oxy-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}bis-({4,4'-dimeth-oxy-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenol}manganese(III)) bis-(hexa-fluorido-phosphate).

Project description:In the title complex, [Mn(2)(C(19)H(20)N(2)O(4))(2)(C(19)H(22)N(2)O(4))(2)](PF(6))(2), the Mn(III) ion is coordinated by two O [Mn-O = 1.855?(2) and 1.887?(2)?Å] and two N [Mn-N = 1.982?(3) and 1.977?(3)?Å] atoms from the tetra-dentate Schiff base ligand and a coordinated axial ligand [Mn-O = 2.129?(2)?Å]. The centrosymmetric dimer contains two Jahn-Teller-distorted Mn(III) ions, each in a nearly octa-hedral geometry, connected through two phenolate bridges from two ligands. There are two stereogenic centers. The methyl group and the H atom attached to the middle propane C atom are disordered over two positions with occupancy factors in the ratio 0.58:0.42. The crystal is therefore a mixture of two diasteroisomers, viz. RS/SR and RR/SS. In the axial ligand, the two benzene rings form a dihedral angle of 56.97?(5)° and the dihedral angle between the two MnNC(3)O chelate rings is 2.98?(12)°

| S-EPMC2977226 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data