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Cyclic alternating ring-opening metathesis polymerization (CAROMP). Rapid access to functionalized cyclic polymers.

ABSTRACT: Catalysis of alternating ROMP with (H(2)IMes)Cl(2)Ru=CHPh(OiPr), the second generation Hoveyda-Grubbs catalyst, provided an entirely cyclic alternating polymer. Conditions for the cyclic AROMP were used to prepare a polymer in which one of the repeat units bore a primary alkyl chloride that was used for further elaboration.

SUBMITTER: Song A

PROVIDER: S-EPMC2933648 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Cyclic alternating ring-opening metathesis polymerization (CAROMP). Rapid access to functionalized cyclic polymers.

Song Airong A Parker Kathlyn A KA Sampson Nicole S NS

Organic letters 20100901 17

Catalysis of alternating ROMP with (H(2)IMes)Cl(2)Ru=CHPh(OiPr), the second generation Hoveyda-Grubbs catalyst, provided an entirely cyclic alternating polymer. Conditions for the cyclic AROMP were used to prepare a polymer in which one of the repeat units bore a primary alkyl chloride that was used for further elaboration. ...[more]

PMID: 20684538

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Alternating Ring-Opening Metathesis Polymerization Provides Easy Access to Functional and Fully Degradable Polymers.

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