Ontology highlight
ABSTRACT:
SUBMITTER: Koren-Selfridge L
PROVIDER: S-EPMC2934784 | biostudies-literature | 2010
REPOSITORIES: biostudies-literature
Koren-Selfridge Liza L Query Ian P IP Hanson Joel A JA Isley Nicholas A NA Guzei Ilia A IA Clark Timothy B TB
Organometallics 20100101 17
Metal boryl complexes have received significant attention in the literature in recent years due to their role as key intermediates in a number of metal-catalyzed borylation reactions. The ligand scaffold is known to have a significant impact on the observed reactivity of these metal boryl complexes. A synthetic strategy to access ruthenium boryl analogues of the Shvo metal-ligand catalysts is described. Heating a precursor to Shvo's catalyst (1) with bis(catecholato)diboron at 50 °C provided rut ...[more]