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Skeletal diversity via cationic rearrangements of substituted dihydropyrans.

ABSTRACT: Substituted dihydropyrans, easily accessed from a commercially available glycal, undergo acid-catalyzed rearrangement to provide highly functionalized isochroman and dioxabicyclooctane scaffolds.

SUBMITTER: Medeiros MR

PROVIDER: S-EPMC2937281 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Skeletal diversity via cationic rearrangements of substituted dihydropyrans.

Medeiros Matthew R MR Narayan Radha S RS McDougal Nolan T NT Schaus Scott E SE Porco John A JA

Organic letters 20100701 14

Substituted dihydropyrans, easily accessed from a commercially available glycal, undergo acid-catalyzed rearrangement to provide highly functionalized isochroman and dioxabicyclooctane scaffolds. ...[more]

PMID: 20550144

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