Ontology highlight
ABSTRACT:
SUBMITTER: Fisher TJ
PROVIDER: S-EPMC2942783 | biostudies-literature | 2010 Oct
REPOSITORIES: biostudies-literature
Fisher Thomas J TJ Dussault Patrick H PH
Tetrahedron letters 20101001 42
Hypochlorites efficently dehydrate hydroperoxyacetals to furnish the corresponding esters. The reaction, which can be accomplished with stoichometric Ca(OCl)(2) or with catalytic amounts of t-BuOCl, appears to involve formation and heterolytic fragmentation of secondary chloroperoxides, species not previously described in solution chemistry. ...[more]