Experimental characterization and computational study of unique C,N-chelated lithium dianions.
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ABSTRACT:
SUBMITTER: Gruver JM
PROVIDER: S-EPMC2945296 | biostudies-literature | 2010 Sep
REPOSITORIES: biostudies-literature
Publications
Experimental characterization and computational study of unique C,N-chelated lithium dianions.
Gruver Jocelyn M JM West Scott P SP Collum David B DB Sarpong Richmond R
Journal of the American Chemical Society 20100901 38
The structure of a unique C,N-chelated dilithio dianion has been established as a solvated monomeric species using a combination of NMR and computational techniques. The highly ordered structure of the dianion may be important in its reactivity in an oxidative C-N bond-forming process. ...[more]
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