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Experimental characterization and computational study of unique C,N-chelated lithium dianions.


ABSTRACT: The structure of a unique C,N-chelated dilithio dianion has been established as a solvated monomeric species using a combination of NMR and computational techniques. The highly ordered structure of the dianion may be important in its reactivity in an oxidative C-N bond-forming process.

SUBMITTER: Gruver JM 

PROVIDER: S-EPMC2945296 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Experimental characterization and computational study of unique C,N-chelated lithium dianions.

Gruver Jocelyn M JM   West Scott P SP   Collum David B DB   Sarpong Richmond R  

Journal of the American Chemical Society 20100901 38


The structure of a unique C,N-chelated dilithio dianion has been established as a solvated monomeric species using a combination of NMR and computational techniques. The highly ordered structure of the dianion may be important in its reactivity in an oxidative C-N bond-forming process. ...[more]

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