Browse
Submit Data
Databases
API
Help

Dataset Information

15 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dichlorido(6-methyl-2,2'-bipyridine-?N,N')zinc(II).

ABSTRACT: In the mol-ecule of the title compound, [ZnCl(2)(C(11)H(10)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the 6-methyl-2,2'-bipyridine ligand and by two Cl atoms. There are ?-? contacts between the pyridine ring and the five-membered ring, and also between the pyridine rings, [centroid-centroid distances = 3.685?(3) and 3.757?(3)?Å, respectively].

SUBMITTER: Ahmadi R

PROVIDER: S-EPMC2959229 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dichlorido(6-methyl-2,2'-bipyridine-κN,N')zinc(II).

Ahmadi Roya R Kalateh Khadijeh K Ebadi Amin A Amani Vahid V Khavasi Hamid Reza HR

Acta crystallographica. Section E, Structure reports online 20080913 Pt 10

In the mol-ecule of the title compound, [ZnCl(2)(C(11)H(10)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the 6-methyl-2,2'-bipyridine ligand and by two Cl atoms. There are π-π contacts between the pyridine ring and the five-membered ring, and also between the pyridine rings, [centroid-centroid distances = 3.685 (3) and 3.757 (3) Å, respectively]. ...[more]

PMID: 21201019

Similar Datasets

Dichlorido(6,6'-dimethyl-2,2'-bipyridine-?N,N')zinc(II).

Project description:In the title compound, [ZnCl(2)(C(12)H(12)N(2))], the complete mol-ecule is generated by crystallographic mirror symmetry, with the Zn atom and both chloride ions lying on the reflecting plane, yielding a distorted ZnN(2)Cl(2) tetra-hedral coordination for the metal ion. In the crystal, there are ?-? contacts between the pyridine rings [centroid-centroid distance = 3.7857?(17)?Å].

| S-EPMC2970226 | biostudies-literature

Dichlorido(5,5'-dimethyl-2,2'-bipyridine-?N,N')zinc(II).

Project description:The asymmetric unit of the title compound, [ZnCl(2)(C(12)H(12)N(2))], contains two independent mol-ecules. The Zn(II) atoms are four-coordinated in distorted tetra-hedral configurations by two N atoms from 5,5'-dimethyl-2,2'-bipyridine and two terminal Cl atoms. In the crystal structure, inter-molecular C-H?Cl hydrogen bonds link the mol-ecules. There are C-H?? contacts between the methyl groups and the pyridine and five-membered rings containing Zn(II) atoms; ?-? contacts also exist between the pyridine rings [centroid-centroid distances = 3.665?(5) and 3.674?(5)?Å].

| S-EPMC2960607 | biostudies-literature

Dichlorido(6-methyl-2,2'-bipyridine-?N,N')mercury(II).

Project description:In the mol-ecule of the title compound, [HgCl(2)(C(11)H(10)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a 6-methyl-2,2'-bipyridine ligand and two Cl atoms. There is a ?-? contact between the pyridine rings [centroid-centroid distance = 3.9758?(5)?Å].

| S-EPMC2959542 | biostudies-literature

Dichlorido(6-methyl-2,2'-bipyridine-κ(2)N,N')cobalt(II).

Project description:In the title compound, [CoCl(2)(C(11)H(10)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6-methyl-2,2'-bipyridine ligand and two terminal Cl atoms. Inter-molecular C-H⋯Cl hydrogen bonds and π-π stacking inter-actions between the pyridine rings [centroid-centroid distance = 3.745 (3) Å] are present in the crystal.

| S-EPMC3515097 | biostudies-literature

Dibromido(6-methyl-2,2'-bipyridine-?N,N')zinc(II).

Project description:In the title compound, [ZnBr(2)(C(11)H(10)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a 6-methyl-2,2'-bipyridine ligand and two terminal Br atoms. Weak inter-molecular C-H?Br hydrogen bonds and ?-? stacking inter-actions between the pyridine rings [centroid-centroid distances = 3.763?(5) and 3.835?(6)?Å] contribute to crystal-packing effects.

| S-EPMC2983320 | biostudies-literature

Dichlorido(6,6'-dimethyl-2,2'-bipyridine-?N,N')cobalt(II).

Project description:In the title compound, [CoCl(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6,6'-dimethyl-2,2'-bipyridine ligand and two terminal Cl atoms. Inter-molecular C-H?Cl hydrogen bonds and ?-? stacking inter-actions between the pyridine rings [centroid-centroid distances = 3.788?(1) and 3.957?(1)?Å] are present in the crystal structure.

| S-EPMC2983300 | biostudies-literature

(2,2'-Bipyridine-?N,N')bis-(4-methyl-benzoato-?O,O')zinc(II).

Project description:In the title compound, [Zn(C(8)H(7)O(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by four O atoms from two chelating 4-methyl-benzoate ligands and two N atoms from a 2,2'-bipyridine ligand, displaying a disordered octahedral geometry. C-H?O hydrogen bonds connect the complex mol-ecules into a three-dimensional supra-molecular structure.

| S-EPMC2961165 | biostudies-literature

Dichlorido[2,2'-(oxydimethyl-ene)dipyridine]zinc(II).

Project description:In the title complex, [ZnCl(2)(C(12)H(12)N(2)O)], the Zn(II) atom is coordinated in a distorted trigonal-bipyramidal geometry by two Cl atoms, and one O atom and two N atoms from the 2,2'-(oxydimethyl-ene)dipyridine ligand. In the complex, the two pyridine rings make a dihedral angle of 15.44?(14)°. There is a weak inter-molecular ?-? stacking inter-action between pyridine rings; the centroid-centroid distance is 3.8079?(17)?Å.

| S-EPMC2959519 | biostudies-literature

Redetermination of (2,2'-bipyridine-?N,N')dichlorido-palladium(II) dichloro-methane solvate.

Project description:In the title compound, [PdCl(2)(C(10)H(8)N(2))]·CH(2)Cl(2), the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the 2,2'-bipyridine (bipy) ligand and two chloride ions. The compound displays intra-molecular C-H?Cl hydrogen bonds and pairs of complex mol-ecules are connected by inter-molecular C-H?Cl hydrogen bonds. Inter-molecular ?-? inter-actions are present between the pyridine rings of the ligand, the shortest centroid-centroid distance being 4.096?(3)?Å. As a result of the electronic nature of the chelate ring, it is possible to create ?-? inter-actions to its symmetry-related counterpart [3.720?(2)?Å] and also with a pyridine ring [3.570?(3)?Å] of the bipy unit. The present structure is a redetermination of a previous structure [Vicente et al. (1997 ?). Private communication (refcode PYCXMN02). CCDC, Cambridge, England]. In the new structure refinement all H atoms were located in a difference Fourier synthesis. Their coordinates were refined freely, together with isotropic displacement parameters.

| S-EPMC2969654 | biostudies-literature

(2,2'-Bipyridine-κN,N')bis-(N-ethyl-N-methyl-dithio-carbamato-κS,S')zinc(II).

Project description:The complete mol-ecule of the title compound, [Zn(C(4)H(8)NS(2))(2)(C(10)H(8)N(2))], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bis-ects the central C-C bond of the 2,2'-bipyridine mol-ecule. The metal atom is chelated by two S,S'-bidentate dithio-carbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN(2)S(4) octa-hedral geometry. The methyl and ethyl groups of the anion are statistically disordered.

| S-EPMC2979959 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data