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(±)-N-(3-Hydr-oxy-1,2-diphenyl-prop-yl)-4-methyl-benzene-sulfonamide.

ABSTRACT: In the title compound, C(22)H(23)NO(3)S, the relative stereochemistry of the two stereogenic centres is anti with respect to the H atoms. The mol-ecular packing of the crystal shows a double-strand arrangement, consisting of one strand of (S*,S*) enanti-omers and one strand of (R*,R*) enanti-omers. Both strands lie parallel to each other along the a axis. Each strand is made up of dimers in which the mol-ecules are connected to each other via an inter-molecular O-H?O hydrogen bond between the hydroxyl groups and an O-H?? inter-action with the aromatic ring. These units are then connected to neighbouring dimers via N-H?O hydrogen bonds and C-H?O interactions. Intramolecular C-H?O interactions are also observed.

SUBMITTER: Tong ST 

PROVIDER: S-EPMC2959308 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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(±)-N-(3-Hydr-oxy-1,2-diphenyl-prop-yl)-4-methyl-benzene-sulfonamide.

Tong Sok Teng ST   Barker David D   Choi Ka Wai KW   Boyd Peter D W PD   Brimble Margaret A MA  

Acta crystallographica. Section E, Structure reports online 20080924 Pt 10

In the title compound, C(22)H(23)NO(3)S, the relative stereochemistry of the two stereogenic centres is anti with respect to the H atoms. The mol-ecular packing of the crystal shows a double-strand arrangement, consisting of one strand of (S*,S*) enanti-omers and one strand of (R*,R*) enanti-omers. Both strands lie parallel to each other along the a axis. Each strand is made up of dimers in which the mol-ecules are connected to each other via an inter-molecular O-H⋯O hydrogen bond between the hy  ...[more]

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