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N-[(1S,2S)-2-Amino-1,2-diphenyl-eth-yl]-4-methyl-benzene-sulfonamide [(S,S)-TsDPEN].


ABSTRACT: The crystal structure of the title compound, C(21)H(22)N(2)O(2)S, shows a network of N-H?N and N-H?O hydrogen bonds. The tolyl and 1-phenyl rings are almost mutually coplanar [7.89?(9)°], while the 2-phenyl ring makes a dihedral angle of 50.8?(1) ° with the 1-phenyl ring. An intra-molecular N-H?N hydrogen bond stabilizes the mol-ecular conformation.

SUBMITTER: Schlemmer C 

PROVIDER: S-EPMC3011471 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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N-[(1S,2S)-2-Amino-1,2-diphenyl-eth-yl]-4-methyl-benzene-sulfonamide [(S,S)-TsDPEN].

Schlemmer Claudine C   Schollmeyer Dieter D   Blank Nancy N   Stoye Alexander A   Opatz Till T  

Acta crystallographica. Section E, Structure reports online 20101127 Pt 12


The crystal structure of the title compound, C(21)H(22)N(2)O(2)S, shows a network of N-H⋯N and N-H⋯O hydrogen bonds. The tolyl and 1-phenyl rings are almost mutually coplanar [7.89 (9)°], while the 2-phenyl ring makes a dihedral angle of 50.8 (1) ° with the 1-phenyl ring. An intra-molecular N-H⋯N hydrogen bond stabilizes the mol-ecular conformation. ...[more]

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